High-efficiency microphotooxidation using milliwatt LED sources

John M. Carney; Reagan J. Hammer; Martin Hulce; Chad M. Lomas; Dayna Miyashiro

doi:10.1016/j.tetlet.2010.11.071

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High-efficiency microphotooxidation using milliwatt LED sources

Journal article

Peer reviewed

High-efficiency microphotooxidation using milliwatt LED sources

John M. Carney, Reagan J. Hammer, Martin Hulce, Chad M. Lomas and Dayna Miyashiro

Tetrahedron Letters, Vol.52(2), pp.352-355

01/12/2011

DOI: https://doi.org/10.1016/j.tetlet.2010.11.071

Abstract

Biochemistry

Drug Discovery

Organic Chemistry

Inexpensive milliwatt light emitting diode (LED) sources allow energy- and atom-efficient microphotochemical reactions. Thus, sources constructed from three 120 mW 5 mm diameter 627 nm LED's enable μmol-mmol scale methylene blue-sensitized singlet oxygen photooxidations of various arenes and cyclopentadienones using a 3-5 M excess of oxygen in 82-98% yields.

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Title: High-efficiency microphotooxidation using milliwatt LED sources
Creators: John M. Carney (Author) - Creighton University
Reagan J. Hammer (Author) - Creighton University
Martin Hulce (Author) - Department of Chemistry
Chad M. Lomas (Author) - Creighton University
Dayna Miyashiro (Author) - Creighton University
Additional links: Clark, Terry D.; Potter, Joshua D.; Larson, Jennifer M.; Mordeson, John N.; Wierman, Mark J.
Publication Details: Tetrahedron Letters, Vol.52(2), pp.352-355
Series: 52
Number of pages: 4
Identifiers: 991005929015502656
Academic Unit: Chemistry and Biochemistry
Language: English
Resource Type: Journal article

High-efficiency microphotooxidation using milliwatt LED sources

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