Quantum chemical calculations showed that oxaphosphetes with an equatorial oxygen atom may be intermediates in the reaction of acetylenic derivatives and phosphine oxides with electron-releasing substituent(s) on the phosphorus atom.
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Title
Structure and stability of oxaphosphetes formed as intermediates in the reaction of tertiary phosphine oxides and acetylenic derivatives
Creators
György Keglevich (Author) - Budapest University of Technology and Economics
Tamás Körtvélyesi (Author) - University of Szeged
Henrietta Forintos (Author) - Budapest University of Technology and Economics
Sándor Lovas (Author) - Department of Biomedical Sciences
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Wang, P.P.; Tyan, J.C.-Y.; Kaneda, K.
Publication Details
Journal of the Chemical Society. Perkin Transactions 2, Vol.2(10), pp.1645-1646