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Structure and stability of oxaphosphetes formed as intermediates in the reaction of tertiary phosphine oxides and acetylenic derivatives
Journal article   Peer reviewed

Structure and stability of oxaphosphetes formed as intermediates in the reaction of tertiary phosphine oxides and acetylenic derivatives

György Keglevich, Tamás Körtvélyesi, Henrietta Forintos and Sándor Lovas
Journal of the Chemical Society. Perkin Transactions 2, Vol.2(10), pp.1645-1646
2
10/01/2002

Abstract

Chemistry(all)
Quantum chemical calculations showed that oxaphosphetes with an equatorial oxygen atom may be intermediates in the reaction of acetylenic derivatives and phosphine oxides with electron-releasing substituent(s) on the phosphorus atom.

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