Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin; Justin N. Cross; Juan Diwu; Matthew J. Polinski; Eric M. Villa; Thomas E. Albrecht-Schmitt

doi:10.1021/ic301846g

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Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

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Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin, Justin N. Cross, Juan Diwu, Matthew J. Polinski, Eric M. Villa and Thomas E. Albrecht-Schmitt

Inorganic Chemistry, Vol.51(21), pp.11949-11954

11/05/2012

DOI: https://doi.org/10.1021/ic301846g

PMID: 23075083

Abstract

Physical and Theoretical Chemistry

Inorganic Chemistry

Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.

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Title: Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)
Creators: Jian Lin (Author) - University of Notre Dame
Justin N. Cross (Author) - University of Notre Dame
Juan Diwu (Author) - University of Notre Dame
Matthew J. Polinski (Author) - University of Notre Dame
Eric M. Villa (Author) - University of Notre Dame
Thomas E. Albrecht-Schmitt (Author) - Florida State University
Additional links: Wang, P.P.; Dai, J.; Tyan, J.C.-Y.
Publication Details: Inorganic Chemistry, Vol.51(21), pp.11949-11954
Series: 51
Number of pages: 6
Identifiers: 991005930370702656
Academic Unit: Creighton University
Language: English
Resource Type: Journal article

Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

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